Synthetic Route of 1111-67-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article£¬once mentioned of 1111-67-7
One-pot’ synthesis of two molybdenum/tungsten (VI)-copper(I) mixed metal clusters under catalysis of 1,10-phenathroline
Under the catalysis of 1,10-phenathroline (phen), (NH4) 2 M’S4 (M’ = Mo,W) reacts with CuSCN and dppm in mixed solvent MeCN/DMF (1:1) to yield two saddle-shaped clusters [WS 4Cu4(SCN)2 (dppm)3] ?3DMF?2CH3CN (1) and [MoS4Cu4(SCN) 2 (dppm)3]?4DMF (2) (dppm = bis (diphenylphosphino) methane). Compounds 1-2 were characterized by elemental analysis, IR, UV-Vis, 1H NMR, 31P NMR, and single-crystal X-ray diffraction. Each [M’S4]2- (M’ = Mo, W) anion coordinates to four Cu atoms through four bridging S atoms, and all S atoms are coordinated with two Cu atoms. In each cluster the four Cu atoms are almost in one plane, and the M’ atom is above the plane. Cluster 1 was characterized by luminescent with the lambdaem = 545 nm. The possible catalysis mechanism of phenathroline is discussed.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 1111-67-7. In my other articles, you can also check out more blogs about 1111-67-7
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”