Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, SDS of cas: 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. SDS of cas: 1111-67-7In an article, authors is Erdik, E., once mentioned the new application about SDS of cas: 1111-67-7.
Various uncomplexed and complexed Cu(I) salts, Li2CUCl4, Li2CuCl3, Ph2CuLi and PhCu, have been tested as catalysts in the coupling reactions of phenyllithium with 2-chloroethanol, ethyl bromide, 2-chloroethyl tosylate and ethyl tosylate. CuBr.Me2S, CuCN, CuI.PBu3-n and CuI have been found to be most effective and selective catalysts in diethyl ether, respectively, for these couplings. The catalytic activity in Cu(I) catalyzed coupling reactions of phenyllithium depends on the reaction conditions, onthe nucleofugal group, and on the 2-heteroatom functionality of the sub strate.
The catalyzed pathway has a lower Ea, but the net change in energy that results from the reaction is not affected by the presence of a catalyst. In my other articles, you can also check out more blogs about 1111-67-7
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”