Related Products of 1111-67-7, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps. In an article, authors is Muehle, Joerg, once mentioned the application of Related Products of 1111-67-7, Name is Cuprous thiocyanate,molecular formula is CCuNS, is a conventional compound.
CuX-based coordination polymers (X = I, CN, SCN) with diazacrown ethers or cryptands as bridging ligands have been prepared by reaction of CuX with appropriate macrocycle in acetonnitrile/hexane solution at 100C. Whereas [CuI (1,7-DA12C4)] (1) and [CuI(1,10-DA18C6)] (2) (1,7-DA12C4 = 1,7-diaza-12-crown-4, 1,10-DA18C6 = 1,10-diaza-18-crown-6) are both monomeric, ?1[(CuI)2(1,10-DA18C6)] (3) contains infinite chains in which (CuI)2 rings are linked in a mu-N1,N10 manner by thiacrown ether moieties. The distorted tetrahedral coordination of the CuI atoms in 3 is completed by a weak Cu…O interaction (2.393(7) A) to a 1,10-DA18C6 oxygen atom. ? 2[(Cu4I4)(1,10-DAcrypt)2] (4), (1,10-DAcrypt = 1,10-diaza-cryptand [2.2.2]), ? 2[{(CuCN)6(1,7-DA12C4)4]·2CH 3CN (5) and ?2[(CuSCN)2 (1,10-DA18C6] (6) all exhibit lamellar networks with respectively Cu 4I4 cubes, (CuCN)6 hexagons and ?1[(CuSCN)2] double chains as their CuX substructures. 4 can imbibe up to 0.64 mol KNO3/mol cryptand and 6 up to 0.35 mol KNO3/mol 1,10-DA18C6 as a guest lattice. Crystal structures are reported for 1-6, thermal analysis data (TG/DTA) for complexes 2, 3 and 5.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”