Awesome Chemistry Experiments For 16606-55-6

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Related Products of 16606-55-6, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, belongs to copper-catalyst compound. In a article, author is Moghaddam, Firouz Matloubi, introduce new discover of the category.

Nano cobalt-copper ferrite catalyzed regioselective alpha-C(sp(3))-H cyanation of amines: Secondary, tertiary, and drug molecules

Oxidative cyanation of sp(3)C-H bonds at the a position of amines was achieved using CoCuFe2O4 as a catalyst and NaCN as an inexpensive cyanide source at room temperature. CoCuFe2O4 was found to be an active catalyst for Csp [3]-Csp coupling, efficiently delivering valuable alpha-aminonitriles from tertiary/secondary amines in good yields. The corresponding products were obtained with high selectivity toward a position. In addition, functional group tolerance offered the opportunity for application in late-stage functionalization of biologically active molecules. This transformation proceeds convenient on a gram-scale, and the catalyst can be reused for several runs with consistent catalytic activity.

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Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”