Having gained chemical understanding at molecular level, chemistry graduates may choose to apply this knowledge in almost unlimited ways, as it can be used to analyze all matter and therefore our entire environment. 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. category: copper-catalystIn an article, once mentioned the new application about 1111-67-7.
Non-centrosymmetric one- to three-dimensional CuSCN-based coordination polymers with substituted pyrazine or pyrimidine spacer ligands can be prepared by self-assembly in acetonitrile solution at 100C. Both 1?[CuSCN(2NCpyz)2] (1) (2 NCpyz = 2-cyanopyrazine) and 1?[CuSCN(4 HOpym)2] (3) (4 HOpym = 4-hydroxypyrimidine) contain single zigzag CuSCN chains as their central backbone and crystallise in polar space groups (monoclinic Cm and orthorhombic Ama2). In 2?[(CuSCN)2(mu-2Mepyz)] (2) (2Mepyz = 2-methylpyrazine), 1?[(CuSCN)2] staircase double chains are connected by bridging 2 Merpyz ligands to afford a lamellar polymer (triclinic P1). Whereas 2?[CuSCN(5 Brpym)] (4) (5 Brpym = 5-bromopyrimidine) with its honeycomb 2?[CuSCN] layers is chiral (monoclinic P21), both 3D polymers 3?[(CuSCN)2(mu-pym)] (5) and 3?[(CuSCN)3(mu-4 Mepym)] (6) (4 Mepym = 4-methylpyrimidine) contain polar coordination networks (orthorhombic Fdd2 and monoclinic Pc). The CuSCN framework in (5) consists of thiocyanate bridged 1?[CuS] chains, that in 6 of interlocked 2?[CuSCN] and 2?[Cu2S(SCN)] sheets.
Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. A catalyst, does not appear in the overall stoichiometry of the reaction it catalyzes. you can also check out more blogs about Formula: C8H7NO2!, category: copper-catalyst
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”