Can You Really Do Chemisty Experiments About 1111-67-7

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Synthetic Route of 1111-67-7, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. Synthetic Route of 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article, authors is Tzeng, Biing-Chiau£¬once mentioned of Synthetic Route of 1111-67-7

Polyrotaxane frameworks containing N,N?,N?-(4,4?, 4?-nitrilotris(4,1-phenylene))triisonicotinamide: Structural and luminescent properties

The reaction of a C3-symmetric tridentate ligand, N,N?,N?-(4,4?,4?-nitrilotris(4,1-phenylene)) triisonicotinamide (L), with various d10-metal salts of CuI, Cu(SCN), and M(ClO4)2 (M = Zn, Cd) led to four metal-organic materials of {[(Cu2I2)(L)2] ¡¤4DMF¡¤2MeOH}n (1), {[Cu(L)2(NCS) 2]¡¤3DMF}n (2), and {[M(L)2(ClO 4)2]¡¤4EtOH}n (M = Zn 3 and Cd 4), respectively, which have been isolated and structurally characterized by X-ray diffraction studies. The X-ray analysis revealed that the interlocking of the 1-D double-zigzag chains of 1-4 into the macrocycles of the adjacent chains generates a novel 2-D (1-D ? 2-D) polyrotaxane framework. In these 2-D polyrotaxane frameworks, the C3-symmetric tridentate ligand, L, only adopts a mu2-bridging mode, and the third arm is free. In addition, 1-4 are all emissive with dual emissions (431-452 and 558-570 nm) in the solid state at room temperature and at 77 K, which are suggested to be due to an intraligand transition of L based on the high similarities in emission energies to that of L.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”