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The fused heterocyclic compound represented in formula (1) has excellent effectiveness in pest control. (In the formula, A1 represents -NR4-, etc., A2 represents a nitrogen atom, etc., R1 represents an ethyl group, a cyclopropyl group, or a cyclopropylmethyl group, R2 represents -S(O)mR6 or -C(R7)(CF3)2, R4 represents a C1-C6 alkyl group optionally having one or more halogen atoms, R6 represents a C1-C6 haloalkyl group, R7 represents a fluorine atom or a chlorine atom, and m and n each represents 0, 1 or 2.)

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. Product Details of 13395-16-9, Name is Bis(acetylacetone)copper, Product Details of 13395-16-9, molecular formula is C10H16CuO4. In a article,once mentioned of Product Details of 13395-16-9

Copper complexes of corroles have recently been a subject of keen interest due to their ligand non-innocent character and unique redox properties. Here we investigated bis-copper complex of a triply-linked corrole dimer that serves as a pair of divalent metal ligands but can be reduced to a pair of trivalent metal ligands. Reaction of triply-linked corrole dimer 2 with Cu(acac)2 (acac=acetylacetonate) gave bis-copper(II) complex 2Cu as a highly planar molecule with a mean-plane deviation value of 0.020 A, where the two copper ions were revealed to be divalent by ESR, SQUID, and XPS methods. Oxidation of 2Cu with two equivalents of AgBF4 gave complex 3Cu, which was characterized as a bis-copper(II) complex of a dicationic triply-linked corrole dimer not as the corresponding bis-copper(III) complex. In accord with this assignment, the structural parameters around the copper ions were revealed to be quite similar for 2Cu and 3Cu. Importantly, the magnetic spin?spin interaction differs depending on the redox-state of the ligand, being weak ferromagnetic in 2Cu and antiferromagnetic in 3Cu.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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SDS of cas: 13395-16-9, You could be based in a university, combining chemical research with teaching; or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries. In an article, authors is Yi, Niannian, once mentioned the application of SDS of cas: 13395-16-9, Name is Bis(acetylacetone)copper,molecular formula is C10H16CuO4, is a conventional compound.

A protocol for the copper-catalyzed oxidative self-coupling of alpha-amino carbonyl compounds has been developed for the synthesis of tetrasubstituted 1,4-enediones (Z -isomers) in moderate to good yields through the cleavage of four sp 3 C-H bonds and the simultaneous formation of one C=C double bond in the alpha-amino carbonyl compound. The strategy has the advantages of using readily available starting materials and of high stereoselectivity.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The reactions of a series of 1,2,3,4-tetrahydropyridin-2-ones (1) with diazoacetates (2) in the presence of copper-bronze catalyst yielded exclusively 3-oxo-2-azabicyclo [4.1.0] heptanes (3 and 4) in excellent yields with high exo-selectivity. Tetrahydropyridin-2-ones (1) with N-alkyl substituents were found to be more reactive than N-aryl substitutents. Among the various copper catalysts studied, copper(II) triflate was found to be the best catalyst while rhodium chloride, ruthenium chloride did not catalyze the reaction. The application of ultrasonic radiation enhanced the reaction rate and allowed the reactions to be conducted at room temperature.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 13395-16-9 is helpful to your research.

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The magnetic properties of chalcogenide spinel CuCr2Se4 nanocrystals have been studied as a function of crystallite size (15-30 nm). A solution-based method is used for the facile synthesis of the nanocrystals with good size control. They have close to cubic morphology with a narrow size distribution and exhibit superparamagnetic behavior at room temperature. The Curie temperature and saturation magnetization of the nanocrystals are lower as compared with the bulk and decrease with decreasing nanocrystal size. A similar trend is observed in the paramagnetic state for the Curie-Weiss temperature and effective magnetic moment. The low temperature magnetization behavior can be qualitatively explained by spin glass dynamics.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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When developing chemical systems it’s of course important to gain a deep understanding of the chemical reaction process. COA of Formula: C10H16CuO4, Name is Bis(acetylacetone)copper, COA of Formula: C10H16CuO4, molecular formula is C10H16CuO4. In a article,once mentioned of COA of Formula: C10H16CuO4

Catalytic decomposition of cyclohexyl and 1-methylcyclohexyl peroxides in the presence of 3d-metal acetylacetonates was studied.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Modeling chemical reactions helps engineers virtually understand the chemistry, optimal size and design of the system, and how it interacts with other physics that may come into play. Quality Control of Bis(acetylacetone)copper. Introducing a new discovery about 13395-16-9, Name is Bis(acetylacetone)copper

A selective CVD system used to deposit the central metal of a volatile complex preferentially on catalytically active substrate surfaces was examined.Copper(II) acetylacetonate was vaporized in a flow of hydrogen and decomposed on Ni, Pd, and Al plates in order to deposit metallic copper.When a Ni plate was used as the substrate, deposition of metallic copper occurred at temperatures in the range 130-180 deg C only on the substrate surfaces.The formation of an ultrathin film of Cu of uniform thickness was confirmed.On a Pd substrate, the formation of an ultrathin Cu film of uniform thickness was also observed.On an Al substrate, however, deposition occurred nonselectively at temperatures above 160 deg C, not only on the substrate surface, itself, but also on the wall of the glass tube as well as the quartz wool surrounding the Al plate.In addition, the formation of fine particles of Cu, instead of thin film, was found to exist on the substrate.Because the deposition of Cu took place on catalytically active surfaces selectively, the deposition was considered to proceed by a catalytic hydrogenation of the C=O bond of the ligand, thus detaching it from the Cu ion and allowing it to decompose the complex and deposit Cu metal.

Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 13395-16-9 is helpful to your research.

Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Preparation of epitaxial YBa2Cu3O7 (YBCO) films on cerium oxide-buffered sapphire (r-cut alpha-Al2O3) substrates by an excimer-laser-assisted metalorganic deposition (ELAMOD) is reported. The ELAMOD process has been developed to bring about the advantage of shorter heating time than that in the conventional metalorganic deposition; the coated films are irradiated by an excimer laser beam before firing. We initiated the ELAMOD-YBCO process using a homogenized 8-mm-square laser beam which irradiates the coated surface in a fixed substrate mode. In order to extend the process applicable to large-area films, a scan irradiation mode was employed and a high critical-current density over 6 MA/cm2 has been observed. In the process, an appropriate choice of laser energy is difficult but crucial to obtain YBCO films with high superconducting properties. Then, laser irradiation from backside of the substrate was examined and proved to be beneficial to extend the experimental window of the laser energy. Moreover, a newly developed ELAMOD process using a 90-mm-wide line-beam is also reported which has a potential ability for large-area applications.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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We synthesized uniform Cu2O coated Cu nanoparticles from the thermal decomposition of copper acetylacetonate followed by air oxidation and used these nanoparticles as catalysts for Ullmann type amination coupling reactions of aryl chlorides.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Chemical research careers are more diverse than they might first appear, as there are many different reasons to conduct research and many possible environments. Reference of 13395-16-9. Introducing a new discovery about 13395-16-9, Name is Bis(acetylacetone)copper, The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis.

Copper thin films were prepared by a low-temperature atmospheric pressure chemical vapour deposition method. The raw material was copper (II) acetylacetonate. At a reaction temperature above 220 C, polycrystalline copper films can be obtained by hydrogen reduction of the raw material. The resistivity of the film was close to that for bulk copper.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”