Category: 13395-16-9

Bis(acetylacetone)copper, cas is 13395-16-9, it is a common heterocyclic compound, the copper-catalyst compound, its synthesis route is as follows.

Complex (6) C26H33Cu2N5O14 (FW = 734.66) was prepared by refluxing a hot ethanolic solution of the copper(II) complex (2), (473 mg, 1 mmol) with a hot ethanolic solution of the copper acetyl acetonate (188 mg, 1 mmol). The reaction mixture was refluxed for three hours with stirring. The precipitate so formed, was filtered off, washed with ethanol and dried in vacuum desiccators over CaCl2, Yield 72%, 5.29 gm. Color: Dark brown, m.p. > 300, Elemental Analyses. Calc.: C, 42.51; H, 4.53; N, 9.53; Cu, 15.30; Found: C, 42.21; H, 4.43; N, 9.66; Cu,16.97. IR (KBr, cm-1), 3448(br) nu(H2O), 1685 nu(C=OAcAc), 1670 nu(C=OAcetyl), 1602 nu(C=Nimine), 1570 nu(C=Noxime), 1285 nu(C-OAcAc), 1168 nu(N-O), 670, nu(M-O), 628 nu(M?O), 572 nu(M-N), 510 nu(M?N). Molar conductance (Lambda) is 28.20 Omega-1 cm2 mol-1.

As the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; El-Tabl, Abdou S.; Shakdofa, Mohamad M.E.; Whaba, Mohammed Ahmed; Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy; vol. 136; PC; (2015); p. 1941 – 1949;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Bis(acetylacetone)copper, cas is 13395-16-9, it is a common heterocyclic compound, the copper-catalyst compound, its synthesis route is as follows.

Under a nitrogen atmosphere, copper acetylacetonate (0.9 mmol) was dissolved in 25 mL of dichloromethane, followed by addition of 1,10-phenanthroline (0.9 mmol). The reaction solution was stirred at room temperature for 48 hours and then concentrated in vacuo. The resulting solid was washed with 25 mL of n-pentane and recrystallized with dichloromethane and n-pentane to obtain Catalyst 3. The method of the invention produces this compound in a yield of up to 75%

13395-16-9 is used more and more widely, we look forward to future research findings about Bis(acetylacetone)copper

Reference£º
Patent; Chinese Academy Of Sciences Lanzhou Chemical Physics Institute Suzhou Institute; Li Yuehui; Wang Hua; Dong Yanan; Ke Lisitian¡¤shanduofu; (20 pag.)CN108017557; (2018); A;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Bis(acetylacetone)copper, cas is 13395-16-9, it is a common heterocyclic compound, the copper-catalyst compound, its synthesis route is as follows.

General procedure: In a typical synthesis of Cu40Ag60, 0.45mmol Cu(acac)2 and 0.35 Ag (ac) was mixed with 3mL of OAm, 1 mL of OAc and 11mL of ODE. All synthesis was conducted in a four-necked glass reactor allowing the precise temperature control and inert gas atmosphere under dark conditions. Firstly, the mixture was heated to 60C and kept at this temperature for 10min. Then, the mixture was heated to 180C and kept at this temperature for 30min before it was cooled down to room temperature. After cooling, the resultant reaction mixture was collected with hexane (2mL) and the NPs were separated by centrifugation (8500rpm, 12min) after adding isopropanol (40mL). To further purify the yielded CuAg NPs, the product was centrifuged (8500rpm, 12min) one more time with ethanol (40mL). Finally, the remaining product was dispersed in hexane (10mL) for further use. By using the same recipe and varying metal precursor amounts, two different compositions of CuAg NPs were synthesized. Reductive mixing of 0.3mmol Cu(acac)2 and 0.5 Ag(ac) resulted in Cu30Ag70 NPs and mixing 0.6mmol Cu(acac)2 with 0.4 Ag (ac) led to Cu60Ag40. Synthesis of Ag NPs was conducted with the same recipe without using Cu precursor.

13395-16-9 is used more and more widely, we look forward to future research findings about Bis(acetylacetone)copper

Reference£º
Article; Balkan, Timucin; Kuecuekkececi, Hueseyin; Kaya, Sarp; Metin, Oender; Zarenezhad, Hamaneh; Journal of Alloys and Compounds; vol. 831; (2020);,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

A common heterocyclic compound, the copper-catalyst compound, name is Bis(acetylacetone)copper,cas is 13395-16-9, mainly used in chemical industry, its synthesis route is as follows.

General procedure: CZTS nanoparticles were synthesized at different temperatures(220-320 C) for 3 hours and for variousreaction times (2-5 hours) at 240 C, usinghigh-temperature arrested precipitation in the coordinatingsolvent, oleylamine (OLA).15 Under the reactiontime of 3 hours, the reactants for synthesis ofCZTS nanoparticles didn?t dissolve enough in OLA.

As the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Kim, Donguk; Kim, Minha; Shim, Joongpyo; Kim, Doyoung; Choi, Wonseok; Park, Yong Seob; Choi, Youngkwan; Lee, Jaehyeong; Journal of Nanoscience and Nanotechnology; vol. 16; 5; (2016); p. 5082 – 5086;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

A common heterocyclic compound, the copper-catalyst compound, name is Bis(acetylacetone)copper,cas is 13395-16-9, mainly used in chemical industry, its synthesis route is as follows.

The monodisperse CuPd alloy NPs with composition controlwere synthesized by using a modified version of our estab-lished recipe for the CoPd alloy NPs [14]. In a typical synthesis of Cu75Pd25NPs, copper(II) acetylacetonate (0.35 mmol, 90 mg)and palladium(II) acetylacetonate (0.1 mmol, 31 mg) were dis-solved in 3 mL of OAm in a 10 mL of glass vial. In a four-necked glass reactor that allows to study under inert atmosphere,200 mg of MB was dissolved in 3 mL of OAm and 7 mL of 1-octadecene at 80C under magnetic stirring. Next, the metal precursor mixture was quickly injected into the reactor under argon environment. The reaction was then proceed for 1 h before cooled down to room temperature. Then, the colloidal NPs mixture was transferred into two separate centrifuge tubeand acetone/ethanol (v/v = 7/3) was added into the tubes. TheNP product was separated by centrifugation at 8500 rpm for10 min.

As the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Guengoermez, Kuebra; Metin, Oender; Applied Catalysis A: General; vol. 494; (2015); p. 22 – 28;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

A common heterocyclic compound, the copper-catalyst compound, name is Bis(acetylacetone)copper,cas is 13395-16-9, mainly used in chemical industry, its synthesis route is as follows.

General procedure: In a typical synthesis of Cu40Ag60, 0.45mmol Cu(acac)2 and 0.35 Ag (ac) was mixed with 3mL of OAm, 1 mL of OAc and 11mL of ODE. All synthesis was conducted in a four-necked glass reactor allowing the precise temperature control and inert gas atmosphere under dark conditions. Firstly, the mixture was heated to 60C and kept at this temperature for 10min. Then, the mixture was heated to 180C and kept at this temperature for 30min before it was cooled down to room temperature. After cooling, the resultant reaction mixture was collected with hexane (2mL) and the NPs were separated by centrifugation (8500rpm, 12min) after adding isopropanol (40mL). To further purify the yielded CuAg NPs, the product was centrifuged (8500rpm, 12min) one more time with ethanol (40mL). Finally, the remaining product was dispersed in hexane (10mL) for further use. By using the same recipe and varying metal precursor amounts, two different compositions of CuAg NPs were synthesized. Reductive mixing of 0.3mmol Cu(acac)2 and 0.5 Ag(ac) resulted in Cu30Ag70 NPs and mixing 0.6mmol Cu(acac)2 with 0.4 Ag (ac) led to Cu60Ag40. Synthesis of Ag NPs was conducted with the same recipe without using Cu precursor.

As the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Balkan, Timucin; Kuecuekkececi, Hueseyin; Kaya, Sarp; Metin, Oender; Zarenezhad, Hamaneh; Journal of Alloys and Compounds; vol. 831; (2020);,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Bis(acetylacetone)copper, cas is 13395-16-9, it is a common heterocyclic compound, the copper-catalyst compound, its synthesis route is as follows.

A yellow solution of H4L (0.30mmol, 0.068g) in dmf (6mL) was added to a turquoise solution of Cu(acac)2 (0.30mmol, 0.079g) in dmf (20mL). The immediately formed green solution was refluxed for 3h and left for slow evaporation. X-ray quality blue crystals of 3¡¤1.5dmf were formed after 2months, which were filtered off and dried under vacuum. (Yield: 0.053g, ?60%). The solid was analyzed as solvent free. C44H56Cu4N4O18 requires: C, 44.67; H, 4.77; N, 4.73%. Found: C, 44.49; H, 4.74; N, 4.70. FT-IR (KBr pellets, cm-1): 3553(s), 3477(s), 3414(s), 1638(s), 1617(vs), 1578(s), 1553(s), 1533(s), 1462(w), 1413(m), 1384(m), 1355(s), 1275(s), 1189(s), 1020(s), 937(s), 782(s), 684(m), 653(w), 613(s), 480(m), 455(s).

With the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Lazarou, Katerina N.; Savvidou, Aikaterini; Raptopoulou, Catherine P.; Psycharis, Vassilis; Polyhedron; vol. 152; (2018); p. 125 – 137;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

Bis(acetylacetone)copper, cas is 13395-16-9, it is a common heterocyclic compound, the copper-catalyst compound, its synthesis route is as follows.

A mixture of 1.05 g (4 mmol) Cu(AcAc)2, 0.44 g (2 mmol) Zn(OAc)2, 0.38 g (2 mmol) SnCl2, and 20 ml OLA were added into a 100 ml three-neck round-bottom reaction flask connected to a nitrogen gas cylinder. The mixture solution was always stirred vigorously in the flask purged with high pure N2 gas (99.999%), during the whole synthesis. After heated at 130 C for 30 min, the mixture solution became brownish. The brownish solution was injected with 8 ml of sulfur – OLA solution (1 M), then heated at the reaction temperature T reaction 240-280 C for 1 h. When its color changed from dark brownish into blackish, the mixture solution (or product) was cooled down to room temperature (RT) and added with 15 ml of toluene for dispersing by sonication. To washing or purifying the product, 40 ml of ethanol was firstly added to let the nanoparticles flocculate and precipitate; then precipitates of nanoparticles were collected by centrifuging at 4000 rpm for 20 min and the supernatant liquid was removed; the collected precipitates were dispersed in toluene again by sonication; then ethanol was added for precipitates, new precipitates were collected again by centrifuging. The above process was repeated for three times. The final precipitates (or CZTS nanoparticles) were divided into two parts: (1) CZTS nanoparticles dispersed in toluene to form a stable ink solution and (2) CZTS power dried in a vacuum oven.

With the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Zhou, Min; Gong, Yanmei; Xu, Jian; Fang, Gang; Xu, Qingbo; Dong, Jianfeng; Journal of Alloys and Compounds; vol. 574; (2013); p. 272 – 277;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

The copper-catalyst compound, name is Bis(acetylacetone)copper,cas is 13395-16-9, mainly used in chemical industry, its synthesis route is as follows.

General procedure: The monodisperse CuPd alloy NPs with composition controlwere synthesized by using a modified version of our estab-lished recipe for the CoPd alloy NPs [14]. In a typical synthesis of Cu75Pd25NPs, copper(II) acetylacetonate (0.35 mmol, 90 mg)and palladium(II) acetylacetonate (0.1 mmol, 31 mg) were dis-solved in 3 mL of OAm in a 10 mL of glass vial. In a four-necked glass reactor that allows to study under inert atmosphere,200 mg of MB was dissolved in 3 mL of OAm and 7 mL of 1-octadecene at 80C under magnetic stirring. Next, the metal precursor mixture was quickly injected into the reactor under argon environment. The reaction was then proceed for 1 h before cooled down to room temperature. Then, the colloidal NPs mixture was transferred into two separate centrifuge tubeand acetone/ethanol (v/v = 7/3) was added into the tubes. TheNP product was separated by centrifugation at 8500 rpm for10 min.

As the rapid development of chemical substances, we look forward to future research findings about 13395-16-9

Reference£º
Article; Guengoermez, Kuebra; Metin, Oender; Applied Catalysis A: General; vol. 494; (2015); p. 22 – 28;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.13395-16-9,Bis(acetylacetone)copper,as a common compound, the synthetic route is as follows.

Under a nitrogen atmosphere, copper acetylacetonate (0.9 mmol) was dissolved in 25 mL of dichloromethane, followed by addition of 1,10-phenanthroline (0.9 mmol). The reaction solution was stirred at room temperature for 48 hours and then concentrated in vacuo. The resulting solid was washed with 25 mL of n-pentane and recrystallized with dichloromethane and n-pentane to obtain Catalyst 3. The method of the invention produces this compound in a yield of up to 75%

The synthetic route of 13395-16-9 has been constantly updated, and we look forward to future research findings.

Reference£º
Patent; Chinese Academy Of Sciences Lanzhou Chemical Physics Institute Suzhou Institute; Li Yuehui; Wang Hua; Dong Yanan; Ke Lisitian¡¤shanduofu; (20 pag.)CN108017557; (2018); A;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”