Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. We’ll be discussing some of the latest developments in chemical about CAS: Related Products of 13395-16-9, Name is Bis(acetylacetone)copper, belongs to copper-catalyst compound, is a common compound. Related Products of 13395-16-9In an article, authors is Patev, once mentioned the new application about Related Products of 13395-16-9.
Bis[ethyl (trifluoroacetyl)acetato]copper(II), [Cu(etfac)2], has been prepared and studied by X-ray crystallography and EPR spectroscopy. The complex is centrosymmetrical and crystallizes in the P21/c space group with two formula units per unit cell. After dissolving of the complex in solid matrix or in suitable solvents some changes are detected in the EPR spectra and are discussed. The EPR spectra of the complex magnetically diluted in the corresponding Pd(II) complex reveal the presence of only one paramagnetic species further denoted as B. However, EPR spectra measured in solution indicate the presence of two different paramagnetic species: (i) non-distorted parent species B, and (ii) rhombic-distorted species A, which prevail in solutions. The A:B species ratio is a function of the solvent and temperature. The [Cu(etfac)2] adduct with 4-(dimethylamino)pyridine has also been studied and found to crystallize in the C2/c space group. The adduct EPR spectrum monitored in solution shows the presence of only one paramagnetic species.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”