Extracurricular laboratory:new discovery of Bis(acetylacetone)copper

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Solution-based synthesis and characterization of Cu2ZnSnS 4 nanocrystals

(Figure Presented) Recent advances have been made in thin-film solar cells using CdTe and CuIn1-xGaxSe2 (CIGS) nanoparticles, which have achieved impressive efficiencies. Despite these efficiencies, CdTe and CIGS are not amenable to large-scale production because of the cost and scarcity of Te, In, and Ga. Cu2ZnSnS4 (CZTS), however, is an emerging solar cell material that contains only earth-abundant elements and has a near-optimal direct band gap of 1.45-1.65 eV and a large absorption coefficient. Here we report the direct synthesis of CZTS nanocrystals using the hotinjection method. In-depth characterization indicated that pure stoichiometric CZTS nanocrystals with an average particle size of 12.8 ¡À 1.8 nm were formed. Optical measurements showed a band gap of 1.5 eV, which is optimal for a single-junction solar device.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”