Let¡¯s face it, organic chemistry can seem difficult to learn. 1111-67-7. Especially from a beginner¡¯s point of view. Like 1111-67-7, Name is Cuprous thiocyanate. In a document type is Article, introducing its new discovery.
Copper-Mediated [(Diethylphosphono)difluoromethyl]thiolation of alpha-Bromo Ketones
We report herein a straightforward access to alpha-[(diethoxyphosphoryl)difluoromethyl]thiolated ketones. The methodology, which involves the nucleophilic [Cu]CF2PO(OEt)2 species, has allowed the formation of the targeted compounds in moderate to high yields by using a simple procedure. This method represents a convenient alternative to the known approaches for the introduction of this emergent fluorinated motif.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”