One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, HPLC of Formula: CCuNS, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS
A novel two-dimensional CuSCN network templated by 2,2?-dimethyl-1, 1?-(butane-1,4-diyl)bis(1H-imidazol-3-ium) cations
The cation-templated self-assembly of 1,4-bis(2-methyl-1Himidazol-1-yl) butane (bmimb) with CuSCN gives rise to a novel two-dimensional network, namely catena-poly[2,2?-dimethyl-1,1?-(butane-1,4-diyl)bis(1H-imidazol-3- ium) [tetra-mu2-thiocyanato-kappa4S: S;kappa4S:N-dicopper(I)]], {(C12H20N 4)[Cu2-(NCS)4]}n. The CuI cation is four-coordinated by one N and three S atoms, giving a tetrahedral geometry. One of the two crystallographically independent SCN- anions acts as a mu2-S:S bridge, binding a pair of CuI cations into a centrosymmetric [Cu2(NCS)2] subunit, which is further extended into a twodimensional 44-sql net by another kind of SCN – anion with an end-to-end mu2-S:N coordination mode. Interestingly, each H2bmimb dication, lying on an inversion centre, threads through one of the windows of the two-dimensional 44-sql net, giving a pseudorotaxane-like structure. The two-dimensional 44-sql networks are packed into the resultant three-dimensional supramolecular framework through bmimb-SCN N-H…N hydrogen bonds.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. HPLC of Formula: CCuNS, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 1111-67-7, in my other articles.
Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”