13395-16-9, Name is Bis(acetylacetone)copper, belongs to copper-catalyst compound, is a common compound. 13395-16-9In an article, authors is Anac, Olcay, once mentioned the new application about 13395-16-9.
Reactions of alpha,beta-Enones with Diazo Compounds: Part 4: Reaction Pathways from (Z)- and (E)-alpha,beta-Enones with Dimethyl Diazomalonate
In this study, (E)- and (Z)-enones carrying only a phenyl substituent at their C(beta) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”