Related Products of 1111-67-7, Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. Mentioned the application of 1111-67-7, Name is Cuprous thiocyanate.
Three Cu-based coordination polymers (CPs), including [Cu II(N- eta 1-NCS) 2(O- eta 1-DMF) 2(mu 2-3,3′-bptz)] n (1), [Cu I(1,3- mu 2-NCS)(mu 2-3,3′-bptz)] n (2) and [(Cu I(1,3- mu 2- NCS))(mu 2-4,4′-bptz)] n (3) (DMF = N, N-dimethyl formamide, 3,3′-bptz = 3,6-bis(3-pyridyl)tetrazine and 4,4′-bptz = 3,6-bis(4-pyridyl)tetrazine) have been successfully constructed by solution diffusion reactions by using Cu(NO 3) 2.3H 2O or CuNCS and KNCS with 3,3′-bptz / 4,4′-bptz ligands, respectively. The resulting crystalline materials have been characterized by the single-crystal X-ray diffraction analyses, elemental analyses, FT-IR spectra, thermogravimetric analyses and powder X-ray diffraction (PXRD). Single crystal X-ray analyses revealed that CP 1 is organized in one-dimensional (1D) chain in which the Cu(II) ions are coordinated by eta 1-NCS – anions and eta 1-DMF molecules, and linked by mu 2-3,3′-bptz bridging ligands. CPs 2 and 3 are structural isomers. CP 2 exhibits two-dimensional (2D) (4,4)-plane-like network in which Cu(I) ions are linked by mu 2-NCS – and mu 2-3,3′-bptz ligands. In CP 3, Cu(I) ions are connected by mu 2-NCS – and mu 2-4,4′-bptz ligands to form 2D saw-tooth wavy network. In addition, the photoluminescence properties of CPs 1-3 were also investigated in the solid state at room temperature.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”