Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. SDS of cas: 13395-16-9, Name is Bis(acetylacetone)copper, SDS of cas: 13395-16-9, molecular formula is C10H16CuO4. In a article，once mentioned of SDS of cas: 13395-16-9
Skeletal rearrangements of arylborane complexes mediated by redox reactions: thermal and photochemical oxidation by metal ions
A variety of metal salts have been found to undergo reduction by thermal and photochemical interaction with tetraarylborate salts and with neutral alkyl- and aryl-borane complexes.In the cases of Cu2+, Cu+, Ni2+, Co2+, Pd2+, Pt2+, Ag+, Zn2+, Hg2+, Sn2+, Pb2+ and Rh3+ salts, such photochemical reductions with NaBPh4 led to the deposition of the free metal, while a number of binary mixtures of metal salts led to the codeposition of both metals, sometimes as true alloys, under such photoreduction.In the course of these reductions the arylboratereductants underwent oxidative coupling of the aryl groups to form biaryls in a strictly intra-ionic (for BAr4-) or intramolecular (Ar3B) manner respectively.Individual studies of the photochemistry of the tetraarylborate anion itself, of cuprous tetraphenylborate and of the triphenylborane-pyridine complex have adduced evidence for a gamut of reactive intermediates capable of serving as the photoreductant for metal ions, such as triarylborane radical anions, diarylborate(I) anions or arylborenes, 7-borabicycloheptadiene anions or neutral complexes and finally arylborohydride anions or arylboron hydrides.The role of these intermediates both in the photoinduced skeletal rearrangements of arylboranes and in the concomitant reduction of metal ions is discussed in critical detail.Key words: Boron; Aryl; Oxidation; Copper; Nickel; Zinc
Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. A catalyst, does not appear in the overall stoichiometry of the reaction it catalyzes. you can also check out more blogs about HPLC of Formula: C4H2Cl2N2!, SDS of cas: 13395-16-9
Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”