Chemistry can be defined as the study of matter and the changes it undergoes. 1111-67-7. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS, introducing its new discovery.
Three pillared-layered inorganic-organic hybrid polymers with efficient luminescence
Three pillared-layered inorganic-organic hybrid polymers, namely, [Cu2(4,4?-Hbpt)(SCN)2]n (1), [Cd(4,4?-Hbpt)(SCN)2]n (2), and [Cd(4,4?-Hbpt)(SCN)2¡¤CH3CN]n (3) were synthesized via layer diffusion methods. In all three complexes, there exist 2-D neutral wave-like d10 metal thiocyanate layers (for 1, [Cu2(SCN)2]n, and for 2 and 3, [Cd(SCN)2]n) with (4, 4) topology, which are further connected by bidentate 4,4?-Hbpt ligands to form 3-D structures with the primitive cubic topology. The results of photoluminescence and thermogravimetric analyses indicate that the three complexes are good candidates as luminescent materials. This paper provides a strategy to synthesize a novel family of pillared-layered inorganic-organic hybrid polymers constructed with layered d10 metal thiocyanate layers and conjugated organic spacers at the molecular engineering level, as well as the discovery of new patterns of crystallization at the crystal engineering level.
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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”