13395-16-9, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Bis(acetylacetone)copper, cas is 13395-16-9,the copper-catalyst compound, it is a common compound, a new synthetic route is introduced below.
Complex (6) C26H33Cu2N5O14 (FW = 734.66) was prepared by refluxing a hot ethanolic solution of the copper(II) complex (2), (473 mg, 1 mmol) with a hot ethanolic solution of the copper acetyl acetonate (188 mg, 1 mmol). The reaction mixture was refluxed for three hours with stirring. The precipitate so formed, was filtered off, washed with ethanol and dried in vacuum desiccators over CaCl2, Yield 72%, 5.29 gm. Color: Dark brown, m.p. > 300, Elemental Analyses. Calc.: C, 42.51; H, 4.53; N, 9.53; Cu, 15.30; Found: C, 42.21; H, 4.43; N, 9.66; Cu,16.97. IR (KBr, cm-1), 3448(br) nu(H2O), 1685 nu(C=OAcAc), 1670 nu(C=OAcetyl), 1602 nu(C=Nimine), 1570 nu(C=Noxime), 1285 nu(C-OAcAc), 1168 nu(N-O), 670, nu(M-O), 628 nu(M?O), 572 nu(M-N), 510 nu(M?N). Molar conductance (Lambda) is 28.20 Omega-1 cm2 mol-1.
Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Bis(acetylacetone)copper, 13395-16-9
Reference£º
Article; El-Tabl, Abdou S.; Shakdofa, Mohamad M.E.; Whaba, Mohammed Ahmed; Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy; vol. 136; PC; (2015); p. 1941 – 1949;,
Copper catalysis in organic synthesis – NCBI
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”