Electric Literature of 16606-55-6, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 16606-55-6, Name is (R)-4-Methyl-1,3-dioxolan-2-one, SMILES is O=C1OC[C@@H](C)O1, belongs to copper-catalyst compound. In a article, author is Hijazi, Ahmed K., introduce new discover of the category.
Catalytic cyclopropanation, antimicrobial, and DFT properties of some chelated transition metal(II) complexes
Transition Metal (II) complexes of general formula [M-II(NH2C2H4NH2)(3)][B(C6F5)(4)](2) (1-6), where (MS Mn, Fe, Co, Ni, Cu, Zn) have been synthesized and characterized in the solid state and in solution using elemental, thermogravimetric analysis, EPR, B-11-NMR and IR spectroscopy. All complexes were used as catalysts for the cyclopropanation reaction with a variety of olefins. Excellent yields up to 93% were obtained using complex 5. All prepared complexes were used as anti-bacterial agents against different types of bacteria (Gram-negative and Gram-positive), and as anti-fungal agents. Complex 6 showed the highest activity with MIC value of 8 mu g/mL against Staphylococcus aureus (Gram-positive bacteria), and of 16 mu g/mL against candida albicans. To get more insights into their structural features, molecular geometries of all prepared complexes were fully optimized using density functional theory calculations at the M06-2X/6-311+G** level of theory. (C) 2020 Elsevier B.V. All rights reserved.
Electric Literature of 16606-55-6, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 16606-55-6 is helpful to your research.
Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”