Application In Synthesis of Cuprous thiocyanate, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In an article, authors is Feng, Jian-Jun, once mentioned the application of Application In Synthesis of Cuprous thiocyanate, Name is Cuprous thiocyanate,molecular formula is CCuNS, is a conventional compound.
A copper-catalyzed C-Si bond formation between N-halogenated amides and Si-B reagents is described. This oxidative coupling enables the silylation of C(sp3)-H bonds alpha to an amide nitrogen atom. The utility of the new method is demonstrated for sulfonamides, and N-chlorination with tBuOCl and C-H silylation employing CuSCN/4,4?-dimethoxy-2,2?-bipyridine as catalyst can be performed without purification of the N-Cl intermediate.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”