Top Picks: new discover of Cuprous thiocyanate

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A study on solution deposited CuSCN thin films: Structural, electrochemical, optical properties

A cost-effective successive ionic layer adsorption and reaction (SILAR) method was used to deposit copper (I) thiocyanate (CuSCN) thin films on glass and steel substrates for this study. The deposited thin films were characterized for their structural, morphological, optical and electrochemical properties using X-ray diffraction (XRD), scanning electron microscopy (SEM), UV?visible spectroscopy and VersaSTAT potentiostat. A direct band gap of 3.88 eV and 3.6 eV with film thickness of 0.7 mum and 0.9 mum was obtained at 20 and 30 deposition cycles respectively. The band gap, microstrain, dislocation density and crystal size were observed to be thickness dependent. The specific capacitance of the CuSCN thin film electrode at 20 mV/s was 760 F g?1 for deposition 20 cycles and 729 F g?1 for deposition 30 cycles.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Certain 6-substituted-2-pyridinamines

Certain novel substituted imidazo [1,2-a] pyridines with a substituted amino group at the 2- or 3-position are active anthelmintic agents. The novel compounds are prepared from the appropriate substituted 2-aminopyridine precursor. Compositions which utilize said novel imidazo [1,2-a] pyridines as the active ingredient thereof for the treatment of helminthiasis are also disclosed.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

New explortion of 1111-67-7

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Quality Control of Cuprous thiocyanate, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. Quality Control of Cuprous thiocyanate, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article, authors is Ptaszynski£¬once mentioned of Quality Control of Cuprous thiocyanate

Thermal decomposition of alkali metal, copper(I) and silver(I) thiocyanates

Thermal decomposition of alkali metal thiocyanates of the general formula MSCN (M=Na, K, Rb, Cs), CuSCN and AgSCN has been studied. Thermal analysis curves and diffraction patterns of the solid intermediate, and final, products of their pyrolysis are presented. Gaseous products of the decomposition, SO2 and CO2, were quantified. Thermal, X-ray and chemical analyses have been used to establish the nature of the reactions occurring at each stage of decomposition.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The structural definition of some novel adducts of stoichiometry CuX:dpex:MeCN (2:1:1)(n), X = (pseudo-) halogen, dppx = Ph2E(CH2)xEPh2, E = P, As, Sb

Single-crystal X-ray studies have defined the structures of a number of novel adducts of the form CuX:dpex (2:1), X = (pseudo-)halide, dpex = bis(diphenylpnicogeno)alkane, Ph2E(CH2)xEPh2, E = P, As, of diverse types, solvated with acetonitrile. CuBr:dpem (2:1)2. 2MeCN (E = both P, As) are tetranuclear, derivative of the familiar ‘step’ structure, while CuCl:dpph (MeCN solvate) and CuBr:dppe (MeCN solvate) yield one-dimensional polymers (i.e., x = 1, 2, 6 for dppx, x = m, e, h), as also does CuSCN:dpam (MeCN solvate). In CuI:dpsm:MeCN (3:1:2) (‘dpsm’ = Ph2Sb(CH2)SbPh2), CuI:dpsm (2:1)2 ‘step’ units are connected into an infinite ‘stair’ polymer by interspersed (MeCN)CuI linkers.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Brief introduction of Cuprous thiocyanate

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Recommanded Product: 1111-67-7, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. Recommanded Product: 1111-67-7, Name is Cuprous thiocyanate, molecular formula is CCuNS. In a Article, authors is Still, Ian W. J.£¬once mentioned of Recommanded Product: 1111-67-7

A VERSATILE SYNTHETIC ROUTE TO SUBSTITUTED THIANTHRENES

2,7-Dinitrothianthrene has been prepared by the base-catalyzed cyclization of 2-chloro-5-nitrobenzenethiol and proves to be a versatile starting point for the preparation of several 2,7-disubstituted thianthrenes, both symmetrically and unsymmetrically substituted.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

New explortion of 1111-67-7

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Selective Construction of 2-Substituted Benzothiazoles from o-Iodoaniline Derivatives S8 and N-Tosylhydrazones

Selective construction of 2-substituted benzothiazoles from o-iodoaniline derivatives S8 and N-tosylhydrazone via a copper-promoted [3 + 1 + 1]-type cyclization reaction has been realized. In the protocol, the carbon atom on N-tosylhydrazone could be regulated to construct benzothiazole by changing the reaction system. Furthermore, the transformation has achieved the construction of multiple carbon-heteroatom bonds.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Final Thoughts on Chemistry for Cuprous thiocyanate

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Increasing structure dimensionality of copper(I) complexes by varying the flexible thioether ligand geometry and counteranions

This work focuses on the systematic investigation of the influences of pyrimidine-based thioether ligand geometries and counteranions on the overall molecular architectures. A N-containing heterocyclic dithioether ligand 2,6-bis-(2-pyrimidinesulfanylmethyl)pyridine (L1) and three structurally related isomeric bis(2-pyrimidinesulfanylmethyl)-benzene (L2-L4) ligands have been prepared. On the basis of the self-assembly of CuX (X = I, Br, Cl, SCN, or CN) and the four structurally related flexible dithioether ligands, we have synthesized and characterized 10 new metal-organic entities, Cu 4(L1)2I4 1, Cu4(L1) 2Br4 2, [Cu2(L2)2I 2¡¤CH3CN]n 3, [Cu(L3)I]n 4, [Cu(L3)Br]n 5, [Cu(L3)CN]n 6, [Cu(L4)CN]n 7, [Cu2(L4)I2]n 8, [Cu2(L4)(SCN) 2]n 9, and {[Cu6I5(L4) 3](BF4)¡¤H2O}n 10, by elemental analyses, IR spectroscopy, and X-ray crystallography. Single-crystal X-ray analyses show that the 10 Cu(I) complexes possess an increasing dimensionality from 0D (1 and 2) to 1D (3-5) to 2D (6-9) to 3D (10), which indicates that the ligand geometry takes an essential role in the framework formation of the Cu(I) complexes. The influence of counteranions and pi-pi weak interactions on the formation and dimensionality of these coordination polymers has also been explored. In addition, the photoluminescence properties of Cu(I) coordination polymers 4-10 in the solid state have been studied.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Route scouting and optimization of a potent sulfoximine-based inverse agonist of RORgammat

During our research looking for novel inverse agonists of RORgammat, we identified a potent sulfoximine-based modulator as one of our pre-clinical candidates for the topical treatment for psoriasis. Herein, we describe the various routes we evaluated during the lead generation and optimization phases and the final route chosen for scale-up to deliver the first 100 g of API.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Awesome and Easy Science Experiments about Cuprous thiocyanate

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Synthesis, structure, spectroscopy, and magnetism of two new dinuclear carbonato-bridged Cu(II) complexes

Two new dinuclear mu-CO32- Cu(II) complexes with different coordination modes for the carbonato bridge have been obtained by fixation of atmospheric CO2 and also directly prepared from the carbonate salt. The compounds comprise: [Cu2(mu-CO3)(dpyam)4](ClO4) 2(H2O)4 (1), and [Cu2(mu-CO3)2(dpyam)2](H 2O) (2), (in which dpyam = di-2-pyridylamine). For 1, the carbonate ligand acts as a bridge between two Cu(II) centres showing an anti-anti (mu-eta1-eta1-CO32-) coordination mode with a distorted square-based pyramidal geometry for each Cu(II) environment. Complex 2 involves the di-mu-CO32- bridge with a novel tridentate mu-eta1-eta2-CO32- coordination mode. The geometry around each copper atom is distorted square-based pyramidal. Susceptibility measurements for both complexes show a weak to moderately strong antiferromagnetic coupling with J values of -90.4 and -9.9 cm-1 for 1 and 2, respectively. The tridentate co-ordination mode of the carbonate bridge in 2 has not previously been reported for dinuclear Cu(II) complexes. Also its magnetic behaviour and superexchange pathway are discussed.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Crystal melting and glass formation in copper thiocyanate based coordination polymers

Crystal melting and glass formation of coordination polymers (CPs) and metal-organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4?-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”