Tag: M.W:100-200

In an article, author is Balciunaite, A., once mentioned the application of 16606-55-6, Name: (R)-4-Methyl-1,3-dioxolan-2-one, Name is (R)-4-Methyl-1,3-dioxolan-2-one, molecular formula is C4H6O3, molecular weight is 102.09, MDL number is MFCD00798265, category is copper-catalyst. Now introduce a scientific discovery about this category.

Investigation of hydrogen generation from sodium borohydride using different cobalt catalysts

Effective Co/Cu, CoB/Cu, and CoBM (M = Mo,Zn,Fe)/Cu catalysts were prepared on the copper surface by a simple electroless deposition method using a morpholine borane as a reducing agent in the glycine solution. The activity of the deposited catalysts was investigated for hydrogen generation from an alkaline sodium borohydride solution. It was determined that these synthesized catalysts demonstrated the catalytic activity for the hydrolysis reaction of NaBH4. The lowest obtained activation energy (EA) of the hydrolysis reaction of NaBH4 was 27 kJ mol(-1) for the CoBMo/Cu catalyst. The hydrogen generation rate of 15.30 ml min(-1) was achieved using CoBMo/Cu catalysts at 313 K and it increased similar to 3.5 times with the increase of temperature to 343 K. The highest hydrogen generation rate obtained by CoBMo/Cu films may be related to the hierarchical cauliflower-shaped 3D structures and the high roughness surface area. Moreover, the CoBMo/Cu catalyst showed an excellent reusability. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

If you are interested in 16606-55-6, you can contact me at any time and look forward to more communication. Name: (R)-4-Methyl-1,3-dioxolan-2-one.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Recommanded Product: 2-(2-Bromoethyl)-1,3-dioxolane18742-02-4, Name is 2-(2-Bromoethyl)-1,3-dioxolane, SMILES is C(C1OCCO1)CBr, belongs to copper-catalyst compound. In a article, author is Gupta, Radhika, introduce new discover of the category.

A magnetically retrievable copper ionic liquid nanocatalyst for cyclooxidative synthesis of 2-phenylquinazolin-4(3H)-ones

In the present work, we report the design and fabrication of a copper-containing ionic liquid supported magnetic nanocatalyst via a convenient and straightforward synthetic approach for the formation of 2-phenylquinazolin-4(3H)-ones using o-aminobenzamide and benzaldehydes as the reaction partners. The successful formation and properties of the as-prepared catalyst have been thoroughly investigated using diverse physico-chemical techniques including FT-IR, XRD, FE-SEM, TEM, ICP, VSM, BET and TGA. Using this nanocatalytic system, a variety of 2-phenylquinazolin-4(3H)-ones are synthesized in excellent yields with operational ease and short reaction times in an environmentally preferable solvent under open air and without using any external oxidizing agent. Besides, the catalyst possessed facile magnetic recoverability and remarkable reusability for six consecutive runs without any appreciable decrease in the catalytic efficiency.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 18742-02-4. Recommanded Product: 2-(2-Bromoethyl)-1,3-dioxolane.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, molecular formula is C6H12O3, belongs to copper-catalyst compound. In a document, author is Zhang, Wei, introduce the new discover, Recommanded Product: (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol.

Operando evidence of Cu+ stabilization via a single-atom modifier for CO2 electroreduction

Oxide-derived Cu materials are most commonly used as electrocatalysts for the carbon dioxide reduction reaction (CO2RR). Previous studies have proved that Cu+ and residual subsurface oxygen species can enhance the CO2RR activity; however the stable presence of Cu+ remains a subject of debate. Here, we design a strategy of single-atom Sn anchored on Cu2O nanosheets to stabilize the key Cu+ species for electroreduction of CO2. Operando synchrotron X-ray absorption spectroscopy and statistics analysis distinguish the active Cu+ and reduced Cu+ species, and reveal that the constructed Sn-O-Cu sites with charge transfer can significantly enhance the resistance of copper oxides to reduction. Operando infrared spectroscopy suggests that the survival of Cu+ species on the catalyst surface promotes the adsorption of *CO during the CO2RR, leading to the obvious improvement of CO2-to-CO conversion. Our results demonstrate the role of a single-atom-modifier in both stabilizing Cu+ species and enhancing the CO2RR selectivity of oxide-derived Cu catalysts.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 14347-78-5. Recommanded Product: (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, Formula: C10H12O2, 2568-25-4, Name is Benzaldehyde Propylene Glycol Acetal, SMILES is CC1OC(C2=CC=CC=C2)OC1, belongs to copper-catalyst compound. In a document, author is Wang, Si-Qing, introduce the new discover.

Copper(I)-Catalyzed Asymmetric Vinylogous Aldol-Type Reaction of Allylazaarenes

A vinylogous aldol-type reaction of allylazaarenes and aldehydes is disclosed that affords a series of chiral gamma-hydroxyl-alpha,beta-unsaturated azaarenes in moderate to excellent yields with high to excellent regio- and enantioselectivities. With (R,R-P)-TANIAPHOS and (R,R)-QUINOXP* as the ligand, the carbon-carbon double bond in the products is generated in (E)-form. With (R)-DTBM-SEGPHOS as the ligand, (Z)-form carbon-carbon double bond is formed in the major product. In this vinylogous reaction, aromatic, alpha,beta-unsaturated, and aliphatic aldehydes are competent substrates. Moreover, a variety of azaarenes, such as pyrimidine, pyridine, pyrazine, quinoline, quinoxaline, quinazoline, and benzo[d]imidazole are well-tolerated. At last, the chiral vinylogous product is demonstrated as a suitable Michael acceptor towards CuI-catalyzed nucleophilic addition with organomagnesium reagents.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 2568-25-4. Formula: C10H12O2.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Reference of 2568-25-4, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 2568-25-4, Name is Benzaldehyde Propylene Glycol Acetal, SMILES is CC1OC(C2=CC=CC=C2)OC1, belongs to copper-catalyst compound. In a article, author is Lyu, Zhiheng, introduce new discover of the category.

Kinetically Controlled Synthesis of Pd-Cu Janus Nanocrystals with Enriched Surface Structures and Enhanced Catalytic Activities toward CO2 Reduction

Bimetallic nanocrystals often outperform their monometallic counterparts in catalysis as a result of the electronic coupling and geometric effect arising from two different metals. Here we report a facile synthesis of Pd-Cu Janus nanocrystals with controlled shapes through site-selected growth by reducing the Cu(II) precursor with glucose in the presence of hexadecylamine and Pd icosahedral seeds. Specifically, at a slow reduction rate, the Cu atoms nucleate and grow from one vertex of the icosahedral seed to form a penta-twinned Janus nanocrystal in the shape of a pentagonal bipyramid or decahedron. At a fast reduction rate, in contrast, the Cu atoms can directly nucleate from or diffuse to the edge of the icosahedral seed for the generation of a singly twinned Janus nanocrystal in the shape of a truncated bitetrahedron. The segregation of two elements and the presence of twin boundaries on the surface make the Pd-Cu Janus nanocrystals effective catalysts for the electrochemical reduction of CO2. An onset potential as low as -0.7 V-RHE (RHE: reversible hydrogen electrode) was achieved for C-2(+) products in 0.5 M KHCO3 solution, together with a faradaic efficiency approaching 51.0% at -1.0 V-RHE. Density functional theory and Pourbaix phase diagram studies demonstrated that the high CO coverage on the Pd sites (either metallic or hydride form) during electrocatalysis enabled the spillover of CO to the Cu sites toward subsequent C-C coupling, promoting the formation of C2+ species. This work offers insights for the rational fabrication of bimetallic nanocrystals featuring desired compositions, shapes, and twin structures for catalytic applications.

Reference of 2568-25-4, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 2568-25-4 is helpful to your research.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 18742-02-4, Name is 2-(2-Bromoethyl)-1,3-dioxolane, molecular formula is C5H9BrO2, belongs to copper-catalyst compound. In a document, author is Yang, Yujia, introduce the new discover, Formula: C5H9BrO2.

The key role of reduction process in enhancing the properties and catalytic performance of nanoscale copper particles anchored on three-dimensional macroporous graphene

Optimization of the synthesis process and promotion of the catalytic efficiency are crucial to develop low-cost and effective catalysts for the removal of antibiotics from wastewater. In our previous work, a kind of hybrid material of nanoscale copper particles anchored on three-dimensional macroporous graphene (3D-GN@Cu) has been proved to be a satisfying Fenton-like catalyst. Herein, the self-assembly methods of 3D-GN@Cu preparation by a facile liquid-phase reduction was further investigated with field emission scanning electron microscopy, nitrogen adsorption/desorption isotherms, Raman spectrum analysis, X-ray diffraction, X-ray photoelectron spectroscopy and cyclic voltammograms measurements. The effects of various reduction methods, reduction time and reducing agent dosage on the physicochemical properties and catalytic performances of 3D-GN@Cu were investigated, and the preparation process was optimized. It was found that 3D-GN@Cu prepared by method A with 1.0 M KBH4 for 24 h had the largest surface area, the more defects and the best catalytic properties for the removal of metronidazole. In the combination of experimental results and density functional theory (DFT) calculations, the assembly and optimization law for preparing 3D-GN@Cu and the corresponding mechanisms were illustrated. This provides the theoretical basis and new insights for the preparation of graphene-encapsulated nanometals and related composites, which have a promising application potential in the fields of catalysis, electronics, sensors, bioapplications and environmental pollution control.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 18742-02-4. Formula: C5H9BrO2.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 2568-25-4, Name is Benzaldehyde Propylene Glycol Acetal, molecular formula is C10H12O2, belongs to copper-catalyst compound. In a document, author is Majidi, Leily, introduce the new discover, COA of Formula: C10H12O2.

2D Copper Tetrahydroxyquinone Conductive Metal-Organic Framework for Selective CO2 Electrocatalysis at Low Overpotentials

Metal-organic frameworks (MOFs) are promising materials for electrocatalysis; however, lack of electrical conductivity in the majority of existing MOFs limits their effective utilization in the field. Herein, an excellent catalytic activity of a 2D copper (Cu)-based conductive MOF, copper tetrahydroxyquinone (Cu-THQ), is reported for aqueous CO2 reduction reaction (CO2RR) at low overpotentials. It is revealed that Cu-THQ nanoflakes (NFs) with an average lateral size of 140 nm exhibit a negligible overpotential of 16 mV for the activation of this reaction, a high current density of approximate to 173 mA cm(-2) at -0.45 V versus RHE, an average Faradaic efficiency (F.E.) of approximate to 91% toward CO production, and a remarkable turnover frequency as high as approximate to 20.82 s(-1). In the low overpotential range, the obtained CO formation current density is more than 35 and 25 times higher compared to state-of-the-art MOF and MOF-derived catalysts, respectively. The operando Cu K-edge X-ray absorption near edge spectroscopy and density functional theory calculations reveal the existence of reduced Cu (Cu+) during CO2RR which reversibly returns to Cu2+ after the reaction. The outstanding CO2 catalytic functionality of conductive MOFs (c-MOFs) can open a way toward high-energy-density electrochemical systems.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 2568-25-4. COA of Formula: C10H12O2.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Let¡¯s face it, organic chemistry can seem difficult to learn, Recommanded Product: 2-(2-Bromoethyl)-1,3-dioxolane, Especially from a beginner¡¯s point of view. Like 18742-02-4, Name is 2-(2-Bromoethyl)-1,3-dioxolane, molecular formula is copper-catalyst, belongs to copper-catalyst compound. In a document, author is Xaba, B. S., introducing its new discovery.

The effect of CO2 and H-2 adsorption strength and capacity on the performance of Ga and Zr modified Cu-Zn catalysts for CO2 hydrogenation to methanol

The hydrogenation of CO2 to methanol was performed over Ga2O3 and ZrO2 modified Cu-Zn based catalysts. The prepared catalysts were characterised via P-XRD, ICP-OES, BET, SEM-EDX, H-2-TPR, CO2-TPD, H-2-TPD and H-2-chemisorption. The focus of this investigation was to assess the role of Ga2O3 and ZrO2 promoters on improving the methanol productivity over the Cu-Zn based catalysts. Emphasis was placed on the differences in CO2 and H-2 adsorption capacity and strength due to the introduction of the modifiers, with a focus on the influence of these properties on methanol production. The ZrO2 promoted catalyst delivered a higher methanol space-time yield (STY) in comparison to the Ga2O3 promoted and unpromoted catalysts. The better catalytic performance of the ZrO2 modified catalyst was partly attributed to an improvement of the reducibility. Furthermore, the CO2-TPD results showed that the ZrO2 modified catalyst exhibited the highest CO2 uptake and adsorption strength which contributed to its higher methanol yield. A correlation between the quantity of the spillover hydrogen and methanol yield was also shown to exist for the prepared catalysts. The results obtained from this study suggested that a strong interaction between CO2 and the catalyst surface is crucial to avoid premature desorption of CO2 or its intermediates, thus improving the efficiency of the catalyst. In contrast, an intermediate interaction of H-2 with the catalyst surface facilitates the hydrogen spill-over, which improves the methanol yield.

If you are hungry for even more, make sure to check my other article about 18742-02-4, Recommanded Product: 2-(2-Bromoethyl)-1,3-dioxolane.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , SDS of cas: 14347-78-5, 14347-78-5, Name is (R)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol, molecular formula is C6H12O3, belongs to copper-catalyst compound. In a document, author is Liu, Ya, introduce the new discover.

Behavior of enrichment and migration path of Cu-Ag-Pd-Bi-Pb in the recovery of waste multilayer ceramic capacitors by eutectic capture of copper

Recycling waste multilayer ceramic capacitors (MLCCs) has attracted much attention owing to its rich metal resource and environment pollution. Existing recycling processes have deficiencies in environmental protection, efficiency and metal purity. Capture technology is promising with advantages of efficient enrichment and less pollution, which was applied to recycle metals in this study. In order to study the mechanism for it, the behavior of enrichment and migration of metals in the recovery of waste MLCCs by eutectic capture of copper was discussed. The recovery rates of Ag, Pd and Bi were 87.53%, 100% and 100%, respectively. Alloy (Cu-Ag-Pd-Bi-Pb) and recyclable slag were obtained. There were three phases of Ag, Cu-Pd and Bi-Pb with the analysis of morphology and composition for the alloy. Then the capture mechanism was revealed. The slag and metal separated due to differences in chemical bonds, surface energy, density and viscosity. The interaction of metals was analyzed through phase diagrams and density functional theory. Pd tended to enter Cu phase. Ag and Cu existed as two phases. Bi and Pb neither entered Ag nor Cu phase based on phase diagrams and formation energy. This study provides a theoretical basis for the application of capture technology in metal enrichment. (C) 2020 Elsevier Ltd. All rights reserved.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 14347-78-5. SDS of cas: 14347-78-5.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

In an article, author is Mansoori, Sepideh, once mentioned the application of 18742-02-4, SDS of cas: 18742-02-4, Name is 2-(2-Bromoethyl)-1,3-dioxolane, molecular formula is C5H9BrO2, molecular weight is 181.0278, MDL number is MFCD00003216, category is copper-catalyst. Now introduce a scientific discovery about this category.

Activated biochar supported iron-copper oxide bimetallic catalyst for degradation of ciprofloxacin via photo-assisted electro-Fenton process: A mild pH condition

Iron-copper oxide impregnated NaOH-activated biochar (FeCu/ABC) was successfully fabricated through simple pyrolysis of activated biochar, followed by the impregnation method. The catalytic activity of the bimetallic catalyst was investigated for cipmfloxacin (CIP) degradation through a heterogeneous photo-electro-Fenton process at natural pH. The characterization analyses verified the structural suitability of as-synthesized FeCu/ABC to act as a catalyst for treating CIP. The effects of operating parameters such as Cu/Fe mass ratio, initial pH, catalyst dosage, electrical current and initial concentration of CIP were carefully studied. Complete removal of CIP concentrations of up to 45 mg/L was obtained after 2 h of reaction at Cu/Fe mass ratio of 1:1, pH 5.8, catalyst dosage of 1 g/L, and electrical current of 400 mA. CIP decay followed pseudo-first-order reaction kinetics. The synthesized heterogeneous catalyst exhibited a remarkable catalytic activity at natural pH (92 % mineralization of CIP after 8 h under the optimum conditions). The prepared catalyst possessed great stability and structural integrity for 5 consecutive runs. Furthermore, from a practical point of view, the catalyst exhibited an acceptable performance by oxidizing CIP dissolved in various water matrices such as tap water, river water, and a real sample of wastewater. The possible CIP degradation pathways were also proposed based on the identification of different oxidation by-products.

If you are interested in 18742-02-4, you can contact me at any time and look forward to more communication. SDS of cas: 18742-02-4.

Reference:
Copper catalysis in organic synthesis – NCBI,
,Special Issue “Fundamentals and Applications of Copper-Based Catalysts”