Archives for Chemistry Experiments of Cuprous thiocyanate

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Aromatic isothiazolopyridines: New direct synthetic approaches

Alternative synthetic route to the title ring systems were examined: the isothiazolopyridines 5a,b and 10 were obtained by single step procedures from pyridine derivatives.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

A new application about Cuprous thiocyanate

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Assembly of novel 2D and 3D heterometallic SbIII-CuI polymers based on antimony(III) thiolates as metallothiolato ligands

A new type of neutral heterometallic SbIII-CuI thiolate coordination polymer has been synthesized under solvothermal conditions by using antimony(III) thiolates as metalloligands and CuSCN as the source of the second metal ion. Reaction of [Sb(edt)Cl] (1) (edt = ethane-1,2-dithiolate) with 1 equivalent of CuSCN affords [{Sb2(edt) 2(mu3-S)CuCl(CuSCN)}n] (2), which features a 2D layer consisted of -CuSCNCuSCN-chains and {Sb2(edt) 2(mu3-S)CuCl} units. During the reaction, 1 was converted into a sulfur-bridged dimer Sb(edt)2S, which behaves simultaneously as a bridging and chelating ligand through all of its sulfur atoms to connect four Cu+ ions in the framework structure of 2. Replacement of Cl- in 1 with pymt-gives a new antimony(III) thiolate formulated as [Sb(edt)-(pymt)] (3) (pymt = 2-pyrimidinethiol), which was further treated with CuSCN to afford coordination polymers [{[Sb(edt)(pymt)] 2(CuSCN)3}n] (4) and [{[Sb(edt)(pymt)]-(CuSCN) 2}n] (5). In the assemblies of 4 and 5, the structure of 3 remains intact and the whole compound serves as a multidentate ligand through Sedt and Npymt atoms to Cu+ ions. Complex 4 also contains -CuSCNCuSCN- chains, which are linked by tridentate {Sb(edt)(pymt)} fragments to form a 2D polymer. Complex 5 is a 3D architecture with {Sb(edt)(pymt)} units acting as bidentate bridging ligand to link the (CuSCN)n layers and {(CuSCN)2}n columns. Complexes 2-5 showed optical transitions with band gaps of 2.66 to 3.41 eV, and their optical properties were studied by DFT calculations. Wiley-VCH Verlag GmbH & Co. KGaA, 2009.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Awesome and Easy Science Experiments about Copper(I) oxide

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Disubstituted xanthone carboxylic acid compounds

Compositions containing and methods employing, as the essential ingredient, novel disubstituted xanthone carboxylic acid compounds which are useful in the treatment of allergic conditions. Methods for preparing these compounds and compositions and intermediates therein are also disclosed. 5-Methylsulfinyl-7-isopropoxyxanthone-2-carboxylic acid and 5,7-di(methylsulfinyl)xanthone-2-carboxylic acid are illustrated as representative compounds.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Stability of organometal halide perovskite solar cells and role of HTMs: Recent developments and future directions

Perovskite solar cells (PSCs) have recently emerged as one of the most exciting fields of research of our time, and the World Economic Forum in 2016 recognized them as one of the top 10 technologies in 2016. With 22.7% power conversion efficiency, PSCs are poised to revolutionize the way power is produced, stored and consumed. However, the widespread use of PSCs requires addressing the stability issue. Therefore, it is now time to focus on the critical step i.e. stability under the operating conditions for the development of a sustainable and durable PV technology based on PSCs. In order to improve the stability of PSCs, hole transport materials (HTMs) have been considered as the paramount components. This is due to the fact that most of the organic HTMs possess a hygroscopic and acidic nature that leads to poor stability of the PSCs. This article reviews briefly but comprehensively the environmental stability issues of PSCs, fundamentals, strategies for improvement, the role of HTMs towards stability and various types of HTMs. Also the environmental parameters affecting the performance of perovskite solar cells including temperature, moisture and light soaking environment have been considered.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Front dielectric and back plasmonic wire grating for efficient light trapping in perovskite solar cells

Thin film perovskite solar cells (PSCs) based on (CH3NH3PbI3) have been emerged as good alternatives to conventional silicon solar cells due to their low cost, low fabrication temperature, high carrier collection efficiency, and high-power conversion efficiency (PCE). However, the small thickness of thin film solar cells limits light absorption compared to thick solar cells. In this work, we proposed a theoretical design for enhancing light absorption to achieve maximum theoretical photocurrent using front dielectric and back plasmonic wire grating. Using finite element method (FEM) three-dimensional optical model, the optimum size and periodicity of the studied wire grating nanostructures were identified. Additionally, the electrical model revealed a satisfactory enhancement in PCE over that of the planar structure counterpart. The simulation results showed an average enhancement of 22.4% in total generation rate for the entire simulated wavelength, and more than 85% enhancement in narrow-band wavelength compared to the planar structure counterpart.

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Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Extracurricular laboratory:new discovery of Copper(I) oxide

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6H-Dibenz[b,e][1,4]oxathiepin derivatives

Novel 6H-dibenz[b,e][1,4]oxathiepin derivatives of the formulae I and IA are employed in the treatment and control of allergic conditions such as allergic asthma. STR1

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Oxadiazole and oxadiazoline derivatives

There are described new compounds of formula STR1 in which E is selected from the group consisting of residues of formula STR2 in which R” is selected from the group consisting of amino, vinyl, allyl, ethynyl, C1 -C5 alkyl, C1 -C5 alkoxy, or C1 -C5 alkylthio or a C1 -C5 alkyl group susbstituted by at least one halogen atom; and hydrogen; in which R1 and R2 are each selected from the group consisting of hydrogen, halogen, methyl and ethyl; and R’ is selected from substituted phenyl when R” is other than hydrogen, and phenyl, thienyl and substituted phenyl and thienyl when R” is hydrogen. The compounds are useful in the control of parasites. Certain of the compounds have antimicrobial properties.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Extracurricular laboratory:new discovery of Cuprous thiocyanate

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FUNGICIDAL SUBSTITUTED AZOLES

Disclosed are compounds of Formula (1), including all geometric and stereoisomers, N-oxides, and salts thereof, wherein J is Q2 or R1; X is N, CR2 or CQ3; Y is N or CR3; Z is N or CR4; and Q1, Q2, Q3, R1 R2 and R3 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (1) and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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THERAPEUTIC COMPOUNDS AND COMPOSITIONS

Compounds of general formula I: and compositions comprising compounds of general formula I that modulate pyruvate kinase are described herein. Also described herein are methods of using the compounds that modulate pyruvate kinase in the treatment of diseases.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

Archives for Chemistry Experiments of Cuprous thiocyanate

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Syntheses, crystal structures and luminescent properties of two one-dimensional coordination polymers [CuX(dmpzm)]n (X=CN, NCS; Dmpzm=bis(3,5-dimethylpyrazolyl)methane)

Reactions of CuX (X=CN, NCS) with bis(3,5-dimethylpyrazolyl)methane (dmpzm) gave rise to two new coordination polymers [CuX(dmpzm)]n (X=CN (2), NCS (3)). Compounds 2 and 3 were characterized by elemental analysis, IR spectra and X-ray crystallography. The molecular structure of 2 has a one-dimensional zigzag chain of [CuCN(dmpzm)] units while that of 3 consists of a one-dimensional single-strand spiral chain of [CuNCS(dmpzm)] units. The luminescence properties of CuX (X=I (1), CN (2), NCS (3)) adducts of dmpzm along with free dmpzm were also investigated.

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Reference£º
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”