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Cadmium oxide codoped with Cu and Gd ions powders were synthesised by simultaneous thermal co-decomposition of a mixture of cadmium acetate dihydrate, bis(acetylacetonato)copper, and tris(acetylacetonato)gadolinium(III) complexes. The mass ratio of Cu/Cd is fixed while the Gd/Cd mass ratio varied systematically. The purpose of the present study is to prepare powders having room temperature ferromagnetic (RT-FM) properties. Thus, an amount from each powder was annealed in hydrogen atmosphere in order to study its influence on the magnetic properties. X-ray fluorescence (XRF) and X-ray diffraction (XRD) methods confirm the purity and the formation of single nanocrystalline structure of the as-prepared powders, thus, both Cu and Gd ions were incorporated into CdO lattice forming solid solutions. Magnetic measurements reveal that all doped CdO powders gained paramagnetic (PM) properties where the susceptibility increases linearly with increasing dopant Gd content; the measured effective magnetic moment of doped Gd3+ was 7muB. Furthermore, the created RT-FM is dependent on the Gd% doping level. Also, it was found that the hydrogenation of the powders slightly enhances their PM properties and strongly enhances or creates RT-FM. For hydrogenated CdO powder doped with 3.1% Gd, the coercivity (Hc), remanence (Mr), and saturation magnetization (Ms) were 283.2 Oe, 2.04 memu/g, and 6.67 memu/g, respectively. Also, under hydrogenation, the values of Hc, M r, and Ms were increased by ?145%, 476%, and 131%, respectively in comparison with as prepared. Thus it was proved, for the first time, the possibility of production of CdO with RT-FM, where magnetic characteristics can be tailored by doping and post treatment under H2 atmosphere, thus a new potential candidate to be used as a dilute magnetic semiconductor (DMS).

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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The chemical synthesis of a high-Tc Ba2YCu3O7-delta superconductor was investigated through the organometallic route, using Ba metal, Y(OPri)3, and Cu-alkoxides or Cu-acetylacetonate as starting materials.Chemically homogeneous submicron powders of single phase Ba2YCu3O7-delta were successfully prepared at 750 deg C by controlled partial hydrolysis metal alkoxides.The utilization of ozone for favorable decomposition of Ba2YCu3O7-delta precursors was found to have a remarkable effect on suppressing the formation of Ba CO3 and lowering the formation temperature of Ba2YCu3O7-delta to about 650 deg C.The single phase Ba2YCu3O7-delta ceramics exhibited superconductivity at approximately 83 K (Tc end).

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Cubic CuFeS2 nanocrystals (NCs) have been obtained via a facile colloidal chemistry approach and they show remarkable catalytic activity in the reduction of I3-. Dye sensitized solar cells (DSSCs) with CuFeS2 NCs as counter electrodes (CEs) display a power conversion efficiency of 8.10% comparable to that of a cell with Pt as the CE (7.74%) under the same conditions.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Copper-based quaternary chalcogenide semiconductor Cu2ZnGeS 4 and Cu2ZnGeSe4 nanocrystals have been synthesized successfully via a simple and convenient one-pot phosphine-free solution approach. Oleylamine was used as both the solvent and reductant for Se or S and benefited the formation of homogeneous quaternary nanocrystals. Scanning transmission electron microscopy-EDS elemental mapping confirms the uniform spatial distribution of four elements in nanocrystals. UV-Vis absorption spectra of Cu2ZnGeS4 and Cu2ZnGeSe4 nanocrystals show strong photon absorption in the entire visible range. The photoresponsive behavior indicates the potential application of Cu 2ZnGeSe4 nanocrystals in solar energy conversion systems.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Inorganic nanostructures: Alloyed Cu2ZnSn(S1-xSe x)4 wurtzite nanocrystals (10nm in size) with a varying composition (x=0-1) were synthesized using a colloidal hot injection route. A photoluminescence (PL) emission study of these nanocrystals shows a compositionally tunable band-gap ranging between 0.9-1.4eV that directly correlates to the sulfur-to-selenium ratio (see picture). Copyright

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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(Figure Presented) Recent advances have been made in thin-film solar cells using CdTe and CuIn1-xGaxSe2 (CIGS) nanoparticles, which have achieved impressive efficiencies. Despite these efficiencies, CdTe and CIGS are not amenable to large-scale production because of the cost and scarcity of Te, In, and Ga. Cu2ZnSnS4 (CZTS), however, is an emerging solar cell material that contains only earth-abundant elements and has a near-optimal direct band gap of 1.45-1.65 eV and a large absorption coefficient. Here we report the direct synthesis of CZTS nanocrystals using the hotinjection method. In-depth characterization indicated that pure stoichiometric CZTS nanocrystals with an average particle size of 12.8 ± 1.8 nm were formed. Optical measurements showed a band gap of 1.5 eV, which is optimal for a single-junction solar device.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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We describe the synthesis and fluorescence properties of a Fura-2FF-based fluorescent Ca2+ indicator that can be covalently linked to SNAP-tag fusion proteins and retains its Ca2+ sensing ability after coupling to protein. The Royal Society of Chemistry 2010.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Addressed herein is the composition-controlled catalysis of CuPd alloy nanoparticles (NPs) supported on reduced graphene oxide (RGO) in the hydrolytic dehydrogenation of ammonia borane (AB). Nearly monodisperse CuPd alloy NPs were synthesized by using a surfactant-assisted organic solution phase protocol comprising the co-reduction of acetylacetonate complexes of Pd and Cu by morpholine borane complex in oleylamine and 1-octadecene at 80 C. The presented recipe allowed us to make a composition control over the CuPd alloy NPs. Three different compositions of CuPd alloy NPs (2.7 nm Cu30Pd70, 2.9 nm Cu48Pd52, 3.0 nm Cu75Pd25) could be prepared among which the Cu75Pd25 NPs showed the best catalytic performance in hydrogen generation from the hydrolysis of AB. Among the various support materials tested for as-prepared Cu75Pd25 alloy NPs, the RGO-Cu75Pd25 catalysts showed the highest performance in the hydrolysis of AB. Moreover, the activity of the RGO-Cu75Pd25 catalysts were dramatically enhanced by annealing them at 400 C for 1 h under Ar-H2 (5% H2) gas flow and an unprecedented TOF value of 29.9 min-1 was obtained in the hydrolysis of AB at room temperature. The reported TOF value here is much higher than RGO-Cu (TOF = 3.61 min-1) and even higher than RGO-Pd catalysts (TOF = 26.6 min-1). The detailed kinetics of RGO-Cu75Pd25 catalyzed AB hydrolysis was also studied depending on catalyst concentration, substrate concentration and temperature. The apparent activation energy of the catalytic hydrolysis of AB was calculated to be 45 ± 3 kJ mol-1.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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We describe the synthesis of novel mononuclear and dinuclear copper complexes and an investigation of their behaviour in solution using mass spectrometry (ESI-MS and ESI-MS/MS) and in the solid state using X-ray crystallography. The complexes were synthesized from two widely used diacetylpryridine (dap) ligands, i.e. 2,6-diacetylpyridinebis(benzoic acid hydrazone) and 2,6-diacetylpyridinebis(2-aminobenzoic acid hydrazone). Theoretical calculations (DFT) were used to predict the complex geometries of these new structures, their equilibrium in solution and energies associated with the transformations.

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”

 

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Despite its industrial importance, very limited mechanistic information on the dehydrogenative coupling of dimethyl phthalate has been reported. Herein we report the detailed mechanism for dehydrogenative coupling of dimethyl phthalate catalyzed by [Pd(OAc)2]/[Cu(OAc)2]/1,10-phenanthroline·H2O (phen·H2O). The solution-phase analysis of the catalytic system by XANES shows the active species to be Pd(II), and EXAFS supports the formation of an (acetato)(dimethyl phthalyl)(phen)palladium(II) complex from [Pd(OAc)2]. A formation pathway of tetramethyl 3,3?,4,4?-biphenyltetracarboxylate via disproportionation of independently prepared [Pd(OAc){C6H3(CO2Me)2-3,4}(phen)] is observed with regeneration of [Pd(OAc)2(phen)].

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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”