The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, and theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. 1111-67-7, Name is Cuprous thiocyanate, belongs to copper-catalyst compound, is a common compound. Recommanded Product: 1111-67-7In an article, once mentioned the new application about 1111-67-7.
The cation-templated self-assembly of 1,4-bis(2-methyl-1Himidazol-1-yl) butane (bmimb) with CuSCN gives rise to a novel two-dimensional network, namely catena-poly[2,2?-dimethyl-1,1?-(butane-1,4-diyl)bis(1H-imidazol-3- ium) [tetra-mu2-thiocyanato-kappa4S: S;kappa4S:N-dicopper(I)]], {(C12H20N 4)[Cu2-(NCS)4]}n. The CuI cation is four-coordinated by one N and three S atoms, giving a tetrahedral geometry. One of the two crystallographically independent SCN- anions acts as a mu2-S:S bridge, binding a pair of CuI cations into a centrosymmetric [Cu2(NCS)2] subunit, which is further extended into a twodimensional 44-sql net by another kind of SCN – anion with an end-to-end mu2-S:N coordination mode. Interestingly, each H2bmimb dication, lying on an inversion centre, threads through one of the windows of the two-dimensional 44-sql net, giving a pseudorotaxane-like structure. The two-dimensional 44-sql networks are packed into the resultant three-dimensional supramolecular framework through bmimb-SCN N-H…N hydrogen bonds.
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Reference：
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”